Holdcroft group

Polymers for Electrochemical Energy

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Holdcroft Steven 55Hr_cropped

Steven Holdcroft

Dr. Steven Holdcroft is the former president of the Canadian Society for Chemistry (CSC), a Professor of Chemistry, and former Chair of the Department. He holds a Tier 1 Canada Research Chair in Electrochemical Materials.

He researches ionic polymers, electrochemistry, and hydrogen-based electrochemical technology. He has authored/co-authored 300+ articles. He was the Technical Program Chair of Pacifichem 2010 and Pacifichem 2015 congresses. He was the Group Chair of NSERC’s Evaluation Group 1504 (Chemistry) and served on the Committee for Discovery Research reporting to the Vice President, Research, NSERC. He serves on the Editorial Advisory Board of the journals Energy and Environmental Science, Electrochemical Energy Reviews, and Journal of Power Sources Advances.

In 2017, with three former students, he cofounded Vancouver-based Ionomr Innovations Inc., a thriving 50+ person SFU spin-out commercializing materials (Aemion and Pemion) for clean energy applications.

For services to the community, Dr. Holdcroft was awarded the Macromolecular Science and Engineering Division Award of the Chemical Institute of Canada (CIC) and is a recipient of the Canadian Society of Canada RioTinto Alcan Award for contributions to electrochemical research. He has received the Outstanding Alumni Award from his alma mater (SFU) for Academic Achievement. In 2024 he was awarded the CIC Montreal Medal for his contributions to the Canadian chemical community and in the same year received the prestigious Governor General’s Innovation Award. He is an elected fellow of the Royal Society of Canada

Research

Hydroxyde Ion-Conducting Polymers
Hydroxide Ion-Conducting Polymers

The Holdcroft research group synthesizes and studies hydroxide ion-conducting polymers for alkaline water electrolysis, fuel cells, and CO2 electrolysis (Chem. Soc. Rev., 2024). We invented a new sub-class of polymers, C2-sterically-protected polybenzimidazoliums and polyimidazoliums, which are exceptionally stable under highly caustic conditions at elevated temperatures: Angewandte Chemie (2016), Nature Comm. (2019) and Macromolecules (2023). This work has expanded into organic “Proton Cages”, which afford unprecedented hydroxide ion stability under low RH conditions. Nature Comm. (2024).

Proton-Conducting Polymers
Proton-Conducting Polymers

We study the synthesis of novel proton-containing polymers in order to further understand how polymer structure controls polymer morphology and how morphology facilitates ion-transport. Our work has focused on multi-phenylated, sulfonated polyphenylenes, for which we have patented a method to prepare highly controlled, reproducible macromolecules. Angewandte Chemie (2017), Chem. Mater. (2019), Macromolecules (2019 & 2020), Materials Advances (RSC) (2021), ACS Energy Lett. (2022).

Electrochemical Energy Conversion Devices
Electrochemical Energy Conversion Devices

We fabricate and study electrochemical devices that utilize solid polymer electrolytes. These include fuel cells, water electrolyzers (ACS Energy Lett., 2023), redox flow batteries (J.Mat.Chem.,2024), and electrolyzers for carbon dioxide reduction (Chem. Mater., 2024). Our focus is understanding component and interfacial phenomenon, leading to high performance devices, with a particular emphasis on novel materials based on non-fluorous polymeric membranes. J. Electrochem. Soc. (2020), J. Power Sources Adv. (2020), RSC Adv (2020), ACS Applied Energy Materials (2019), Nature Energy (2021), ACS Catalysis (2022), ChemSusChem (2023). The Holdcroft group is closely affiliated with SFU’s Clean Hydrogen Hub: a 1MW anion exchange membrane water electrolysis facility for advancing emerging clean hydrogen technologies.

Up-Scaled Polymer Synthesis
Up-Scaled Polymer Synthesis and Membrane Fabrication

In 2016, with Holdcroft Research group members (Drs. Holdcroft, Britton, Peckham and Navessin), Ionomr Innovations Inc. was founded to scale and commercialize hydrocarbon solid polymer electrolyte technology. Today, located in Vancouver, Rochester, and Boston, Ionomr employs more than 50 people, and is central to many global research endeavors searching for clean energy technologies. Ionomr has received numerous national and international accolades (Coast Capital Venture Prize (2017), 'Ready to Rocket' list (2017), Hong Kong-Canada Venture Prize (2017), Nouryon International Imagine Chemistry Prize (2018), and the International Start Up Energy Transition (SET) Award) (2019), “Top Product and Market Award”, European F-Cell Conference (2020)., and has been selected from among more than 10,000, as one of one hundred chosen companies selected by the Cleantech Group’s “List of 100 Companies Committed to Taking Action on The Climate Crisis.” Although no longer directly involved in the operations of the company, Holdcroft’s research group continues to study chemistry underpinning large scale polymer synthesis (> 100 kg) and membrane fabrication (>1000 sq. m) leading to green synthetic strategies and high-throughput polymers with highly controlled structures. Energy Environ. Sci. (2016), Macromolecules (2019 & 2020), J. Mem. Sci. (2020), J. Power Sources Adv. (2023).

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